FeSO$_{4}$ as a Novel Li-Ion Battery Cathode (2024)

Chin. Phys. Lett. $FeSO$_{4}$ as a Novel Li-Ion Battery Cathode (1)$ 2021, Vol. 38 $FeSO$_{4}$ as a Novel Li-Ion Battery Cathode (2)$ Issue (6): 068201DOI: 10.1088/0256-307X/38/6/068201

CROSS-DISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY

FeSO$_{4}$ as a Novel Li-Ion Battery Cathode

Jiachao Yang¹, Jian Zou¹, Chun Luo¹, Qiwen Ran¹, Xin Wang¹, Pengyu Chen¹, Chuan Hu¹, Xiaobin Niu¹, Haining Ji^1*, and Liping Wang^1,2*

¹School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 610054, China
²Tianmu Lake Institute of Advanced Energy Storage Technologies, Changzhou 213300, China

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Jiachao Yang,Jian Zou,Chun Luo et al 2021Chin. Phys. Lett.38068201

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Abstract FeSO$_{4}$ has the characteristics of low cost and theoretical high energy density (799 W$\cdot$h$\cdot$kg$^{-1}$ with a two-electron reaction), which can meet the demand for next-generation lithium-ion batteries. Herein, FeSO$_{4}$ as a novel high-performance conversion-reaction type cathode is investigated. We use dopamine as a carbon coating source to increase its electronic conductivity. FeSO$_{4}$@C demonstrates a high reversible specific capacity (512 mA$\cdot$h$\cdot$g$^{-1}$) and a superior cycling performance (482 mA$\cdot$h$\cdot$g$^{-1}$ after 250 cycles). In addition, we further study its reaction mechanism. The FeSO$_{4}$ is converted to Fe and Li$_{2}$SO$_{4}$ during lithium ion insertion and the Fe|Li$_{2}$SO$_{4}$ grain boundaries further store additional lithium ions. Our findings are valuable in exploring other new conversion-type lithium ion battery cathodes.

Received: 17 February 2021 Published: 25 May 2021

PACS:	82.45.Fk	(Electrodes)
	82.47.Aa	(Lithium-ion batteries)
	82.30.-b	(Specific chemical reactions; reaction mechanisms)

Fund: Supported by the Fundamental Research Funds for the Central Universities, China (Grant No.ZYGX2019Z008), and the National Natural Science Foundation of China (Grant No.52072061).

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https://cpl.iphy.ac.cn/10.1088/0256-307X/38/6/068201OR https://cpl.iphy.ac.cn/Y2021/V38/I6/068201

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Articles by authors
$FeSO$_{4}$ as a Novel Li-Ion Battery Cathode (8)$	Jiachao Yang
$FeSO$_{4}$ as a Novel Li-Ion Battery Cathode (9)$	Jian Zou
$FeSO$_{4}$ as a Novel Li-Ion Battery Cathode (10)$	Chun Luo
$FeSO$_{4}$ as a Novel Li-Ion Battery Cathode (11)$	Qiwen Ran
$FeSO$_{4}$ as a Novel Li-Ion Battery Cathode (12)$	Xin Wang
$FeSO$_{4}$ as a Novel Li-Ion Battery Cathode (13)$	Pengyu Chen
$FeSO$_{4}$ as a Novel Li-Ion Battery Cathode (14)$	Chuan Hu
$FeSO$_{4}$ as a Novel Li-Ion Battery Cathode (15)$	Xiaobin Niu
$FeSO$_{4}$ as a Novel Li-Ion Battery Cathode (16)$	Haining Ji
$FeSO$_{4}$ as a Novel Li-Ion Battery Cathode (17)$	and Liping Wang

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